Grafting of swelling clay materials with 3-aminopropyltriethoxysilane

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Grafting of swelling clay materials with 3-aminopropyltriethoxysilane.

The grafting reaction between a trifunctional silylating agent and two kinds of 2:1 type layered silicates was studied using FTIR, XRD, TGA, and 29Si CP/MAS NMR. XRD patterns clearly indicate the introduction of 3-aminopropyltriethoxysilane (gamma-APS) into the clay interlayer. In the natural montmorillonite, gamma-APS adopts a parallel-bilayer arrangement, while it adopts a parallel-monolayer ...

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The Swelling Behavior of Clay - Sulfate Rocks

Clay-sulfate rocks are often encountered in engineering projects such as underground construction and waste repositories. The unique combination of clay swelling and chemical transformation of anhydrite into gypsum results in a swelling behavior that cannot be explained using conventional rock mechanics. The goals of this study are: 1) to investigate the strength characteristics of reconstitute...

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The Rheology of Swelling Clay Dispersions

Nearly all muds, in drilling applications, contain smectite clay minerals, such as montmorillonite or hectorite, which have the remarkable property of swelling in the presence of water. Such systems are known to exhibit long-term gelation and thixotropic behavior, of great importance in applications, depending on clay volume fraction, particle properties (origin of the clay, surface charge, etc...

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Characterization of swelling materials

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ژورنال

عنوان ژورنال: Journal of Colloid and Interface Science

سال: 2005

ISSN: 0021-9797

DOI: 10.1016/j.jcis.2005.02.092